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Why do marshmallows expand in the microwave?

Put a marshmallow in the microwave and within seconds it swells to several times its size, then slumps as it cools. It is a neat bit of kitchen science. Here is what is happening inside.

Sweet tips and how to 2 minute read Updated 26 September 2026 2 sources

In this article
  1. What a marshmallow is made of
  2. What the microwave does
  3. Why it shrinks back
  4. Try it safely

A marshmallow looks solid, but it is mostly bubbles. That is the secret of the trick: see how are marshmallows made?

What a marshmallow is made of

Marshmallows have four basic ingredients: sugar, water, air and a whipping agent, usually a protein such as gelatine. The mixture is whipped into a foam, a liquid with gas bubbles spread all through it, and a marshmallow is about 50% air.

Gelatine does two jobs. It helps trap the air, and it forms a tangled, three dimensional network of long protein chains, which is what makes a marshmallow chewy and springy. That network can stretch: see gelatine in sweets explained

What the microwave does

According to Science Buddies, two things happen at once when a marshmallow is heated in a microwave:

  1. Water turns to vapour. Some of the moisture inside the marshmallow evaporates, adding extra gas to the bubbles.
  2. The gas gets hotter. Warm gas pushes outward with more force than cold gas, so each bubble presses harder on its walls.

Because the gelatine network is stretchy, the bubbles can grow, and the whole marshmallow swells.

Why it shrinks back

Take it out and it starts to slump. As the marshmallow cools, the gas inside the bubbles cools and contracts, and the gelatine firms up again, so the marshmallow shrinks back towards its original size.

Try it safely

This makes a good kitchen experiment, but a microwaved marshmallow gets very hot. Let it cool before anyone touches or eats it, and keep an eye on children. For melting marshmallows on purpose, for rocky road or hot chocolate, see how to melt marshmallows. And for what happens when marshmallows meet an open flame instead, see why do marshmallows catch fire so easily?

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Questions and answers

Why do marshmallows get bigger in the microwave?

Because a marshmallow is full of tiny air bubbles held in stretchy gelatine. The microwave heats its water, which turns to vapour inside the bubbles, and warm gas pushes outward harder, so the bubbles swell and the whole marshmallow puffs up.

Why do microwaved marshmallows shrink again?

As they cool, the gas in the bubbles cools and contracts, and the gelatine firms up again, so the marshmallow shrinks back towards its original size.

Is it safe to microwave marshmallows?

As a supervised experiment, yes, but a microwaved marshmallow gets very hot, so do not touch or eat it straight away.

Sources

  1. Puffing up marshmallows, 29 September 2016, Science Buddies, at Scientific American
  2. Marshmallow, Wikipedia

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